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A structural and mechanistic model for the role of copper in X-ray-induced free radical production is presented. X-rays can produce hydroxyl radicals from Cu(II) and Cu(I) via a Fenton-like mechanism and ROS from Cu(II) and Cu(I) can be responsible for the initiation of peroxidation of the resin matrix. Cross-reactivity experiments have been performed to show a direct correlation between the X-ray-induced free radicals produced and the peroxide detected. This correlation demonstrates that the peroxides detected can be attributed to the photochemical generation of hydroxyl radicals from the solid. The generation of hydroxyl radicals from the monomer is also discussed. A mechanism is proposed which presents the kinetics of monomer decomposition in a resin followed by the production of radicals by Cu(II) and Cu(I). The ROS are involved in the radical generation mechanism, but they are not the only radical species produced.Cameron has only just won the Conservative leadership, the PM has just scored a huge victory in Parliament and he’s sitting down with the EU for a long chat.
And he’s still thinking about cars?
That’s because the Tories have been proposing to cut the tax on new cars for the better part of a decade, and have failed to get the policy across the line.
Here’s just some of what’s going on at the moment.
Before the election, Theresa May promised to cut the rate to 20p in the pound. But it all looked a bit shaky after she took over.
She tried to wriggle out of it on the day of the General Election in a very un-Conservative way, and then reversed herself when she was Prime Minister.
The Tories have been promising to cut the rate for many years and made several statements in Parliament promising that they would do it.
Conservative MPs point out that it’s really easy to promise something because a new car should only cost a maximum of £
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